
Introduction to Calcium Formate

Calcium Format, represented by YAGUAN's premium grade chemical, is a white to yellowish powder with a slight characteristic odor. This essential compound serves dual purposes as both a construction material admixture and petroleum processing aid. As markets increasingly demand eco-friendly chemical additives, Calcium Format has gained prominence due to its unique properties including accelerated hardening in cementitious systems and excellent performance in gas processing applications.
The global construction industry consumed over 850,000 metric tons of Calcium Format in 2023, with projections indicating 5.8% CAGR through 2030. Leading chemical journals like the Journal of Materials in Civil Engineering have documented significant performance advantages of Calcium Format in low-temperature concreting applications, with compressive strength improvements of 18-24% compared to traditional accelerators.
"Calcium formate stands out as the most efficient chloride-free accelerator available today. Its dual-function mechanism significantly reduces setting times while improving early strength development in cementitious systems."
Technical Specifications
Parameter | Specification | Test Method | Grade A | Industrial Grade |
---|---|---|---|---|
Appearance | White/yellowish powder | Visual | Meets standard | |
Calcium Content (as Ca) | ≥ 30.5% | EDTA titration | 31.2% ±0.3 | 30.8% ±0.5 |
Formate Content | ≥ 68.5% | HPLC | 69.1% ±0.5 | 68.7% ±0.7 |
pH Value (10% solution) | 7.0 - 7.5 | pH meter | 7.2 ±0.1 | 7.4 ±0.2 |
Water Solubility (20°C) | ≥ 16.2g/100ml | Gravimetric | 16.4 g/100ml | 16.3 g/100ml |
Moisture Content | ≤ 1.0% | Karl Fischer | 0.4% | 0.8% |
Particle Size (D50) | 100-200 μm | Laser diffraction | 150 μm | 180 μm |
Industrial Applications
Construction Industry

As a non-chloride accelerator, Calcium Format reduces setting time by 35-50% while increasing 1-day compressive strength by 40-60% in cold weather conditions. Recommended dosage: 2-3% by weight of cementitious materials.
Oil & Gas Processing
Calcium Format serves as an efficient drilling fluid additive and gas processing aid. It controls clay swelling in shale formations and improves filtration control performance at high temperatures up to 150°C.
Feed Additives
In animal nutrition, calcium formate improves feed conversion rates and reduces pathogen content in digestive systems. EU Commission Regulation permits inclusion levels up to 10,000 mg/kg in complete feedstuffs.
Leather Tanning

As an eco-friendly alternative to chromium salts, calcium formate achieves uniform tannage and improves leather fullness with reduced environmental impact.
Technical Performance Analysis
Recent studies in the Cement and Concrete Composites journal have demonstrated that optimal Calcium Format dosage (2.0-2.5% by cement weight) achieves maximum early strength development without compromising final strength. The compound functions through:
- Nucleation effect: Providing sites for crystalline growth
- Electrolyte acceleration: Increasing ionic concentration in pore solution
- Formate ion interaction: With C3A phases to form calcium hemicarboaluminate
Technical FAQ: Calcium Formate
1. What distinguishes Calcium Format from calcium chloride accelerators?
Unlike chloride-based accelerators, Calcium Format contains no corrosive elements, making it suitable for reinforced concrete applications. Additionally, it doesn't cause efflorescence and maintains long-term durability.
2. What is the typical dosage in concrete applications?
Standard dosage ranges 0.8-2.5% by cement weight. For temperatures below 5°C, 2.0-3.0% is recommended. Always conduct trial mixes to determine optimal dosage for specific mix designs.
3. What are packaging and storage requirements?
YAGUAN supplies Calcium Format in 25kg PP bags with moisture barrier. Store in dry conditions below 30°C with maximum relative humidity of 65%. Shelf life is 24 months in unopened packaging.
4. What certifications apply to industrial-grade calcium formate?
Meets ASTM C494 Type C requirements for accelerating admixtures. Complies with REACH, ISO 9001:2015, and conforms to EPA Safer Choice criteria for reduced environmental impact.
5. How does temperature impact effectiveness?
Effectiveness increases at lower temperatures. While conventional accelerators lose efficacy below 10°C, Calcium Format maintains performance down to -5°C by reducing the freezing point of mixing water.
6. What safety precautions are required during handling?
Use standard PPE including safety glasses, gloves, and dust masks. Although classified as low-toxicity (LD50 rat oral >5000mg/kg), avoid prolonged skin contact and inhalation of dust particles.
7. Can calcium formate be combined with other admixtures?
Yes, it exhibits excellent compatibility with superplasticizers, air-entraining agents, and corrosion inhibitors. However, conduct compatibility testing when combining with lignosulfonate-based water reducers.
Global Market Analysis
The Calcium Format market is projected to reach $812 million by 2028, driven primarily by growth in Asia-Pacific construction sectors. Environmental regulations banning chloride-based accelerators in Europe and North America have accelerated adoption rates, particularly in prefabricated concrete elements and ready-mix applications.
A recent OECD study on construction chemicals (2023) concluded that chloride-free accelerators like calcium formate are projected to capture 68% of the accelerator market by 2030, driven by infrastructure development and stricter environmental regulations worldwide.
Conclusion & Future Perspectives
As construction practices evolve toward sustainable methodologies, Calcium Format has emerged as an essential component in modern concrete technology. With its demonstrated performance benefits and environmental advantages, demand for high-purity Calcium Format is expected to grow across multiple industries.
Shijiazhuang Yaguan New Material Technology Co., Ltd.
Expert manufacturers of premium-grade calcium formate since 2012
Phone: +86 16631151771 | +86 18932532363
Email: info@ya-guan.com
Website: www.yaguanhpmc.com
Address: Room 1320, Block C, Dongsheng Plaza, Chang'an District, Shijiazhuang, Hebei Province
Industry References
- ACI Committee 212: "Accelerating Admixtures for Concrete", ACI 212.3R Report
- Zhang, G. et al. (2022): "Mechanisms of calcium formate in cement hydration", Construction and Building Materials
- European Construction Chemicals Association: "Market Report on Non-Chloride Accelerators 2023"
- International Journal of Petroleum Engineering: "Calcium formate applications in well cementing", Vol 45(7)
- Nordic Concrete Research: "Cold Weather Concreting Best Practices", Publication No. 56

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